T. Rodionova, V. Komarov, J. Lipkowski
Mar 1, 2010
Citations
0
Influential Citations
28
Citations
Journal
New Journal of Chemistry
Abstract
For the first time the detailed crystal structure of the ionic clathrate hydrate of tetrabutylammonium valerate (C4H9)4NC4H9CO2·39.8H2O has been determined by single crystal X-ray analysis at 150 K. The idealized water–anion host framework consists of five-compartment polyhedral cavities 4T·P and small D cavities. Butyl chains of the cation and the anion of (C4H9)4NC4H9CO2 are included in the five-compartment cavities with displacement of two “inner” host water molecules. The inclusion of the guest entities leads to the distortion of D-cavities which are partially filled by additional “guest” water molecules. The other D-cages are empty. The structure exhibits significant disordering. The adequate model of disordering and inclusion mode of the guest moieties have been obtained. Special features of the crystal structures of ionic clathrate hydrates of tetraalkylammonium carboxylates are discussed.