Q. Shen
Oct 1, 1978
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Influential Citations
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Citations
Journal
Journal of Molecular Structure
Abstract
Abstract The molecular structure of bis(chloromethyl) dimethyl silane has been investigated in the gas phase at a nozzle temperature of 60° C. The molecules exist mainly in the GG form with the presence of 30% (+10%, −20%) AG form. The values of the principal distances (ra) and angles with estimated error limits of 2σ are r(C-H) = 1.093 (0.009) A, r(C-Cl) = 1.801 (0.019) A, r(Si-C) (the average Si-C bond) = 1.875 (0.009) A, ∠(CSiC) = 109.5°, ∠(SiCCl) = 110.5° (0.4), ∠(CCH) = 112.5° (1.8) and φ (the gauche torsion angle relative to 0° for the anti form) = 117.4° (3.8).