J. Contreras, F. Einstein, D. G. Tuck
Nov 15, 1974
Citations
0
Influential Citations
17
Citations
Journal
Canadian Journal of Chemistry
Abstract
The molecular structure of dicholoro(acetylacetonato)-2,2′-bipyridylindium(III) has been determined from three dimensional X-ray data collected by counter methods. The structure has been refined by least-squares techniques to a conventional R factor of 4.3% for the 3524 observed reflections. Crystals of Cl2In(acac)(bipy) are monoclinic, a = 11.340(3), b = 12.198(3), c = 14.330(3) A, β = 120.25(2)°, z = 4, space group P21/c. The chloride ligands are cis, with In—Cl at distances of 2.443(1) and 2.394(1) A; the In—O bond lengths are 2.124(3) and 2.164(3) A, and the In—N bond distances are 2.276(4) and 2.299(4) A.