K. Furue, Toshihide Kimura, N. Yasuoka
Jun 1, 1970
Citations
0
Influential Citations
31
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The molecular structure of dimethyltin chloride N,N-dimethyldithiocarbamate, [(CH3)2-SnCl(S2CN(CH3)2)], has been determined from three-dimensional X-ray diffraction data. The unit-cell dimensions are a=12.67, b=7.64, c=12.11 A, and β=110.3°. The space group is P21/c. Four formula units are contained in a unit-cell. The structure was established by the heavy-atom method. The coordination around the tin atom is a distorted trigonal bipyramid with the following bond distances: Sn–C, 2.17(5) and 2.20(5) A, Sn–Cl, 2.46(1) A and Sn–S, 2.48(1) and 2.79(1) A. Two methyl groups are both in equatorial positions.