J. Grossert, M. Bharadwaj, J. B. Faught
Jun 1, 1980
Citations
0
Influential Citations
4
Citations
Journal
Canadian Journal of Chemistry
Abstract
Thionyl chloride has been shown to react with the zwitterion from dimeric sulfene and triethylamine to give bis(methylsulfonyl dichloromethyl) disulfide, 3. The structure of 3 was determined from its spectral properties and was confirmed by an X-ray crystal structure analysis. Dechlorination of 3 gave bis(methylsulfonylmethyl) disulfide, 4. Raman spectra of 3 and 4, as well as of 5 and 6, two related sulfones derived from 2,4,6-trithiaheptane, are reported.