K. Toman, G. G. Hess
Feb 16, 1973
Citations
0
Influential Citations
11
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The crystal structure of N-[2-(chloromercuri)ethyl]diethylamine, (CH3CH2)2NCH2CH2HgCl, has been determined by X-ray diffraction. The crystals are monoclinic, of space group P21/n; cell dimensions, a = 8.509(4)A, b = 17.052(7)A, c = 6.306(2) A, β = 95.82(15)°. There are 4 molecules per unit cell. With refinement to give R = 0.056, the interatomic distances and angles are CHg, 2.13(3)A; HgCl, 2.36(1)A; CHgCl = 167.1(8)°. The intermolecular NHg distance of 2.77(2)A is less than the Van der Waals contact distance.