I. Sterkhova, I. М. Lazarev, A. Nikonov
Jul 18, 2014
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Journal
Russian Journal of General Chemistry
Abstract
As show the data of IR spectroscopy and quantum-chemical calculations (B3LYP/6-311+G**), N-(silylmethyl)anilines PhNHCH2SiMen(OEt)3−n in inert media have an intramolecular hydrogen bond NH⋯OSi. N-[(Trimethylsilyl)methyl]aniline PhNHCH2SiMe3 in inert solvents exists as a mixture of two conformers close in energy.