W. Scheidt, I. Turowska-Tyrk
Mar 1, 1994
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Inorganic Chemistry
Abstract
The crystal and molecular structure of four-coordinate (octaethylporphinato)cobalt(II) has been determined at 127 K from X-ray diffraction data collected on an area detector. Crystals of Co(OEP) are isomorphous with Fe(OEP), one crystalline form of Ni(OEP), and Cu(OEP); the porphinato core in the series are all planar. The M-N p bond distance order in the series is Fe>Co>Ni