A. Miyazaki, T. Enoki
Jun 1, 2009
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Influential Citations
5
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Journal
New Journal of Chemistry
Abstract
The synthesis, characterization and physical properties of two isopropyl TTF semisquarates, TTFsqiPr and EDT-TTFsqiPr, are reported. These molecules show a solvatochromism effect in solution and electrical conductivity in the solid state in their neutral form. These behaviors can be explained in terms of a small electrical charge redistribution from the TTF-centered HOMO to the semisquarate-centered LUMO of the molecules.