H. Grennberg, V. Langer, J. Bäckvall
1991
Citations
0
Influential Citations
20
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
The mode of attack by acetate on a (π-allyl)palladium complex depends not only on the ligands on palladium, but also on the structure of the complexes; for the bis-[{5-carbomethoxy-(1,2,3-η3)-cyclohexenyl}palladium] complexes, the structures of which were determined by X-ray crystallography and NMR spectroscopy, the cis isomer preferably reacted by external attack whereas the trans isomer, under identical conditions, preferred internal migration.