P. Schmidt, L. Lochmann, B. Schneider
Sep 1, 1971
Citations
0
Influential Citations
11
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract By analysis of vibrational spectra of the sodium and potassium tert -butoxides and of their perdeuterated analogues it was found that potassium tert -butoxide forms cubic tetramers in solution. Sodium tert -butoxide forms similar aggregates only in strongly solvating solvents, whereas in non-polar solvents and in the solid state more complicated aggregates of symmetry lower than T d are formed.