M. Navarro-Ranninger, S. Martínez‐Carrera, S. García-Blanco
1985
Citations
0
Influential Citations
3
Citations
Journal
Polyhedron
Abstract
Abstract A solution of trans-bis(2-aminopyridine)dichloropalladium(II) in DMF and HCl 2 N was left for several weeks. The compound isolated from this solution was identified by X-ray structural analysis as the tetrachloropalladate of meso-3,7-diazonia tricyclo[4.2.2.22,5] dodeca-3,7,9,11-tetraen-4,8 diamine, which contains a dication not previously described in literature. The organic dication is formed by two aminopyridine rings linked by CC bonds whose length is greater (1.61 A) than a normal single CC bond.