Zhipeng Zhao, Kai Zheng, Li Haoran
Oct 1, 2018
Citations
0
Influential Citations
9
Citations
Journal
Inorganica Chimica Acta
Abstract
Abstract We report the synthesis of 3D Ln-CPs [Tb2(ADA)3]n (1a, H2ADA = 1,3-adamantanediacetic Acid), 2D Ln-CPs [Ln2(ADA)3(dmp)2]n·2EtOH·H2O, (Ln3+ = Eu3+, 2a; Gd3+, 2b; Tb3+, 2c; dmp = 4,7-dimethyl-1,10-phenanthroline), and 1D Ln-CPs [Ln(ADA)(HADA)(H2O)]n (Ln3+ = Eu3+, 3a; Gd3+, 3b; Tb3+, 3c), by introducing the ligand H2ADA. The Ln-CPs are characterized by single-crystal X-ray diffraction, PXRD, TGA, elemental analysis and FT-IR. Structure variation is analyzed and suggestions are given for obtaining different types of structures. Luminescence spectra, lifetimes and quantum yields (QYs) are investigated.