Jan Frederick Wappelhorst, Jonathan Wattenberg, C. Strohmann
Mar 1, 2023
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Journal
Acta Crystallographica Section E: Crystallographic Communications
Abstract
Trimethyl({tris[(phenylsulfanyl)methyl]silyl}methoxy)silane (3) is a new ligand for transition-metal coordination chemistry derived from 3-bromo-2,2-bis(bromomethyl)propan-1-ol (1) through silylation and following exchange of bromine groups with NaSPh. Analysis of the Hirshfeld surface shows structure-defining interactions for bromomethylalcohol 1, resulting in intermolecular hydrogen bonds between the hydroxyl groups along the a-axis direction.