L. Qin, Jin Hu, Mingdao Zhang
Oct 8, 2012
Citations
0
Influential Citations
40
Citations
Journal
Chemical communications
Abstract
Two supramolecular isomers, {[Co(L)(OBA)]·H(2)O}(n) (1), {[Co(5)O(2)(L)(2)(OBA)(3)]·7DMF}(n) (2), have been synthesized by one-pot reactions. Compound 1 has a homochiral architecture with low connectivity, and compound 2 is an achiral 3D framework with high 12-connectivity. It is unprecedent to get homochiral and achiral supramolecular isomers by one-pot synthesis.