Gökşin Aydinli, C. Sayil, C. Ibiş
Jan 19, 2010
Citations
0
Influential Citations
5
Citations
Journal
Spectroscopy Letters
Abstract
ABSTRACT 4-Methyl-1-(3,4,4-trichloro-1-cyclohexylsulfanyl-2-nitro-buta-1,3-dienyl) piperidine (2a) and 4-(3,4,4-trichloro-1-decylsulfanyl-2-nitro-buta-1,3-dienyl) morpholine (3b) were synthesized, and their crystal structures were determined. The compound 2a is monoclinic, with space group P21/n, a = 13.2874(8), b = 9.7584(4), c = 15.9479(9) Å, β = 109.110(3)°. V = 1953.91(18) Å3, Z = 4. The cyclohexyl and piperidine rings adopt chair conformation. The compound 3b is monoclinic, with space group P 1 21/c 1, a = 15.7741(3), b = 8.9335(10), c = 16.7775(4) Å, β = 100.7382(13)°. V = 2322.85(8)Å3, Z = 4. The morpholine ring is in a chair conformation. The butadiene unit assumed a configuration close to cissoid in both structures, and their spectroscopic properties were investigated.