Ava Kreider-Mueller, Yi Rong, J. Owen
Jun 25, 2014
Citations
0
Influential Citations
16
Citations
Journal
Dalton transactions
Abstract
The tris(mercaptoimidazolyl)hydroborato complexes, [κ(3)-S2H-Tm(Bu(t))]Na(THF)3 and [κ(3)-S2H-Tm(Ad)]Na(THF)3, which feature t-butyl and adamantyl substituents, have been synthesized via the reactions of the respective 1-R-1,3-dihydro-2H-imidazole-2-thiones with NaBH4 in THF (R = Bu(t), 1-Ad). X-ray diffraction studies indicate that the compounds are monomeric and that the [Tm(R)] ligands coordinate to the metal in a κ(3)-S2H manner via two of the sulfur donors and the hydrogen attached to boron, a combination that is unprecedented for sodium derivatives. Analysis of the tris(mercaptoimidazolyl)hydroborato compounds that are listed in the Cambridge Structural Database has allowed for the formulation of a set of criteria that enables κ(x)-S(x) and κ(x+1)-S(x)H coordination modes to be identified. Furthermore, the various κ(x)-S(x) and κ(x+1)-S(x)H coordination modes have also been analyzed with respect to the conformations of the [Tm(R)] ligands, which differ by rotation of the imidazolethione moieties about the B-N bond.