I. L. Shegal, I. Postovskii
1965
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Influential Citations
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Journal
Chemistry of Heterocyclic Compounds
Abstract
In a study of the aminomethylation of 4-phenyl-1,2,4-triazolinethione-3 (TRIT) it is ascertained that the reaction involves the nitrogen atom of the thioamide group. Salts of TRIT with secondary amines are obtained. It is shown that replacement of N (2) in 1-phenyltetrazolinethione-5 by the=CH- of TRIT leads to a decrease in the acidity of the thione and an increase in the stability of the hydroxymethyl and chloromethyl derivatives.