D. Bigley, R. W. May
1969
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0
Influential Citations
1
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Journal
Journal of The Chemical Society B: Physical Organic
Abstract
The rates of decarboxylation of 2-oxo-1-oxaspiro[4,5]decane-4-carboxylic acid have been measured at five temperatures between 455·6 and 498·9°K. The reaction is first order and homogeneous with ΔH‡= 29·0 kcal. mole–1 and ΔS‡=–13·6 e.u. at 500°K, which suggests a concerted intramolecular mechanism for decomposition.