G. Zhu, Jianjun Huang, Ching-Sung Chi
Jun 1, 1989
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Influential Citations
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Journal
Journal of Fluorine Chemistry
Abstract
Abstract Reaction of fluorine-containing phenyl isocyanide dichloride (1) with different nucleophiles gave a novel series of products, such as 2-chloro-5-trifluoromethylphenylamino-, -perhydropyrimidine (2a), -4,5-dihydrooxazole (2c), -5-trifluoromethylbenzimidazole (4e), hydroxyethyl-2-chloro-5-trifluoromethylphenylcarbamate (7), 2-(2′-chloro-5′-trifluoromethylphenyl)-3-hydroxy -6-trifluoromethylperhydrobenzo-1,2,4-triazine (9). The effect of CF3 group on the ring-closure and the probable reaction mechanism are discussed.