C. Preti, G. Tosi
Nov 1, 1978
Citations
0
Influential Citations
13
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract The interaction of antimony(III) and bismuth(III) trihalides with thiomorpholin-3-one ( tm ), thiomorpholin-3-thione ( ts ), thiazolidine-2-thione ( ttz ) and benzoxazole-2-thione ( bot )has been investigated and the molecular structures of the molecular complexes are discussed on the basis of vibrationaJ spectra. The near and far IR assignments for the solids are discussed with emphasis on the metal—halogen and metal—ligand vibrations. Metal—halogen frequencies suggest that the complexes can be divided into two groups, those with and those without halogen bridges. All the isolated complexes are non-electrolytes in nitrobenzene.