Tianniu Chen, B. Liang, X. Xin
Sep 1, 1997
Citations
0
Influential Citations
13
Citations
Journal
IEEE Journal of Solid-state Circuits
Abstract
Abstract Dichlorobis(4-methylbenzenamine) cobalt(II), nickel(II), and copper(II) were synthesized individually via direct solid–solid reactions between 4-methylbenzenamine and CoCl2·6H2O, NiCl2·6H2O, and CuCl2·2H2O at 20°C and were characterized by spectral studies. Interesting phenomena of the color change and evidently different formation rates of these reactions were observed when performed at 0°C. Furthermore, the concept of “inert” and “labile” complexes is applied for the first time to explain the rates of the substitution reactions in the solid state.