Bai Jian
2005
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Journal
Journal of Yunnan University
Abstract
Hexakis(4-carboxylic acid ethyl ester phenoxy)cyclotriphosphazenes,a new model compound for phosphazene high polymers was synthesized.Its structure was characterized by IR,1HNMR,13CNMR,DEPT and FABMS.The synthetic method was optimized with orthogonal test.The results indicated that the appropriate synthetic method was a follows: the title compound was prepared by reaction of hexachlorocy-clotriphosphazene(1 g) with ethyl 4-hydroxybenzoate(3.5 g) in the presence of K2CO3(2.4 g) as a catalyst and acetone as a solvent at refluxing temperature for 8 h.The yield of the product was 93.9%.