S. M. Rodrigues, Vinícius Palaretti, Viviani Nardini
Nov 5, 2013
Citations
0
Influential Citations
1
Citations
Journal
Journal of Molecular Structure
Abstract
Abstract We describe here the dynamic 1 H NMR studies of dimethyl 2-(triphenylphosphoranylidene) succinate ( 1 ). Phosphorane 1 has a bond presenting slow (in the 1 H NMR time scale) rotation which results in spectra of two isomers at the same time. From the spectral data were calculated the rate constant and thermodynamic parameters for the rotational process.