Xu Wen-yuan
2005
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Journal
Journal of Jiangxi Normal University
Abstract
The alcoholysis of dichlorodimethylsilane has been studied theoretically and experimentally. Both the first and the second steps are very easy to proceed, and the first step is the Rate-Determining-Step of the alcoholyses. Dimethyldiethoxylsilane is the main product. The proportion of ethanol and dichlorodimethylsilane (2 theoretically and 1.8 experimentally) is gained. And the mode of dropping (ethanol dropping into the solvent of dichloromethylsilane) is gained as well. The results of the calculation is consistent with those of the experiments.