S. P. Babailov, E. Zapolotsky
2020
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Journal
Macroheterocycles
Abstract
It was shown that Dy3+ complex with tri-tert-butyl-1,4,7,10-tetraazacyclodecane-1,4,7,10-tetraacetic acid is subjected to irreversible stepwise hydrolysis with the final formation of the complex [Dy(DOTA)]and the hydrolysis rate constants were determined. The temperature sensitivity of the paramagnetic chemical shifts of the signals corresponding to the initial complex and two intermediate hydrolysis products was estimated.