Jin Fang, Baowei Wang, Zhenhua Li
Nov 1, 2003
Citations
0
Influential Citations
13
Citations
Journal
Reaction Kinetics and Catalysis Letters
Abstract
The synthesis of diethyl oxalate from ethyl nitrite and carbon monoxide in gaseous phase has been studied at atmospheric pressure. Kinetics of coupling - regeneration reaction has been determined and the optimization of the reaction has been simulated. The influences of gas impurities has also been studied. Scale-up circulating shows that the concentrate and selectivity were stable in the product and the process is suitable for industrial production.