W. A. Morrison, J. Landgrebe, J. Kleinberg
Jun 3, 1975
Citations
0
Influential Citations
2
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The reaction of di- h 5 -cyclopentadienyltungsten dihydride with benzotrichloride proceeds to produce as the only observed products di- h 5 -cyclopentadienyltungsten dichloride and benzal chloride. The reaction was shown to be first order with respect to Cp 2 WH 2 . The relative rate of reaction increases substantially with the use of 3,4-dichlorobenzotrichloride in place of benzotrichloride as the oxidizing agent.