D. N. Kevill, Byoung-Chun Park, J. Kyong
Oct 28, 2005
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0
Influential Citations
3
Citations
Journal
The Journal of organic chemistry
Abstract
[reaction: see text] Solvolyses of methyl and ethyl chloroglyoxylates proceed about 10(6) times faster than the identical solvolyses of the corresponding chloroformates. The correlation parameters obtained from application of the extended Grunwald-Winstein equation are consistent with an addition-elimination (association-dissociation) mechanism over the full range of solvents, with the addition step being rate determining.