M. Pańkowski, M. Bigorgne
Feb 16, 1972
Citations
0
Influential Citations
9
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Preparation of compound NiI 2 (CO)[P(CH 3 ) 3 ] 2 from Ni(CO) 2 [P(CH 3 ) 3 ] 2 and iodine or NiI 2 [P(CH 3 ) 3 ] 3 and carbon monoxide is presented. These are the first syntheses of dihalogen derivatives of nickel carbonyl. The diiodocarbonylbis(trimethylphosphine) nickel very likely has a trigonal bipyramidal structure with the two axial positions occupied by trimethylphosphine ligands.