J. Bessière, B. Boutevin, A. Bachiri
Nov 1, 1993
Citations
0
Influential Citations
3
Citations
Journal
Journal of Fluorine Chemistry
Abstract
The synthesis of ethyl α-heptadecafluoro-undecanoyloxyacrylate (3), H2CC(OCOCH2CH2C8F17)CO2CH2CH3, has been performed in three steps starting from ethyl bromopyruvate and heptadecafluoro-undecanoic acid, with an overall yield of c. 70%. The homopolymerization and copolymerization of 3 have been easily carried out. From the kinetic study of homopolymerization and copolymerization of monomer 3 with styrene, kp2/kTe and r1, r2, the reactivity ratios of the two monomers, can be determined.