V. Krier, M. A. Jouani, A. Cambon
Nov 2, 1998
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Journal
Journal of Fluorine Chemistry
Abstract
Abstract In this work we report the synthesis of [2-(F-alkyl)ethyl] methylether isothiocyanates by isomerisation of the corresponding thiocyanates. The isothiocyanates are very versatile potential synthetic intermediates. Their reactivity with diamines was investigated and the thioureas obtained, are excellent precursors in the synthesis of new perfluoroalkylated surfactants. The aggregation behaviour of some of these amphiphiles in water were studied. After sonication, the compounds tested form vesicular systems which are identified by freeze fracture electron microscopy.