M. Bredenkamp, C. Holzapfel, F. Toerien
Sep 1, 1992
Citations
0
Influential Citations
23
Citations
Journal
Synthetic Communications
Abstract
Abstract L-Rhamnal (2) is prepared from L-rhamnose (3) by use of an improved generalized Fischer-Zach reaction. L-Rhamnal (2) is then converted to L-(-)-oleandrose (1) by stannylene mediated selective methylation and effective hydration. Benzyl α-L-oleandrose (12) is prepared by selective methylation and deoxygenation of L-rhamnose (3).