Y. Isowa, H. Kurita
Mar 1, 1974
Citations
0
Influential Citations
4
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The reactions of N-tosyl-O-2,4,6-trimethylbenzylhydroxylamine with primary alkyl halides yielded the protected hydroxylamines. The simultaneous cleavage of N-tosyl- and O-2,4,6-trimethylbenzyl groups with hydrogen bromide in acetic acid gave the corresponding N-monoalkylated hydroxylamines such as N-benzylhydroxylamine, 1-amino-3-hydroxyaminopropane and DL-3-hydroxyamino-2-aminopropionic acid.