Jin-Tao Ren
1993
Citations
0
Influential Citations
0
Citations
Journal
Chinese Journal of Organic Chemistry
Abstract
1-Indenyl disilane and disiloxane were synthesized by the reaction of indenyl anionwith chloropentamethyl disilane, 1,2-dichlorotetramethyl disilane and 1,3-dichlorotetramethyldisiloxane respectively. Their structures were characterized by elemental analyses, UV, IR, ~1HNMR and MS. The crystal and molecular structures of 1,2-di (1-indenyl) tetramethyl disi-lane were confirmed by single crystal X-ray diffraction analysis. The crystal belongs tomonoclinic, space group P 2_1/c, with a=0.7462(2), b=1.4439(3), c=0.9789(2) nm; β=108.12(2)°.ν=1.00233nm~3, z=2, D_c=1.14g·cm~(-3). R factor is 0.047, R_w is 0.049.The relationship between spectral properties and molecular structures was discussed.