D. Dong, N. Yu, Wei Zhang
Aug 1, 2016
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Influential Citations
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Journal
Inorganic Chemistry Communications
Abstract
Abstract A novel 1D lead(II) coordination polymer containing anthracene chromophore through the employment of hydrothermal techniques by using 9-anthracenecarboxylic acid and PbI 2 , [Pb(9-aca) 2 (H 2 O) 2 ] ( 1 ) (9-acaH = 9-anthracenecarboxylic acid) has been synthesized and structurally characterized by X-ray single-crystal diffraction as well as by powder X-ray diffraction and elemental analysis. In compound 1 , each PbO 8 polyhedron is linked to each other by oxygen atoms from 9-acaH ligand to form a 1D molecular nanowire with a diameter of 1.22 nm. Surface photovoltage spectroscopy (SPS) and field-induced surface photovoltage (FISPS) of compound 1 indicate that it possesses positive SPV response in the range of 300–800 nm and shows p -type semiconductor characteristic. Luminescent properties of compound 1 reveal that the compound exhibit strong luminescence, ascribed to the charge transfer of anthracene chromophore and the semiconductor 1D Pb 2 O 2 chain.