Leyong Wang, Wen‐Hua Sun, Tianzhu Zhang
Mar 1, 2003
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Journal
Journal of Chemical Crystallography
Abstract
Four new phenoxy imino compounds were synthesized, and the solid-state structures of 1–3 were determined by single-crystal X-ray diffraction study, giving crystallographic data as follows. 2-Acetyl-6-[1-(2,6-diisopropylphenylimino)ethyl]-4-methylphenol (1): a = 13.5893(5) Å, b = 10.5781(4) Å, c = 15.6778(4) Å, β = 113.1804(18)○, P21/c. 2,6-[1-(2,6-Diisopropylphenylimino)ethyl]-4-methylphenol (2): a = 12.1909(5) Å, b = 16.3324(6) Å, c = 15.9456(7) Å, β = 96.990(2)○, P21/c. 2-Acetyl-6-[1-(4-bromine-2,6-dimethylphenylimino)ethyl]-4-methylphenol (3): a = 7.5337(4) Å, b = 10.0457(5) Å, c = 12.6163(4) Å, α = 90.139(3)○, β = 104.003(3)○, γ = 106.485(2)○, P−1. Their molecular structures show that the 2,6-substituted phenyl ring is located approximately orthogonal to the hydroxyphenyl ring with the dihedral angle varying from 85.2○ to 101.4○.