M. Omote, Miyuu Tanaka, A. Ikeda
Apr 18, 2012
Citations
0
Influential Citations
36
Citations
Journal
Organic letters
Abstract
(E)-trimethyl-(3,3,3-trifluoroprop-1-enyl)silane (1) was synthesized as a reagent for use in Hiyama cross-coupling reactions for the production of β-trifluoromethylstyrene derivatives. Cross-coupling of 1 with electronically diverse aryl iodides was achieved by treatment with CsF in the presence of catalytic amounts of palladium to afford the desired products in moderate to good yields.