A. Petrov, N. P. Smetankina, G. Nikishin
Dec 1, 1958
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Journal
Russian Chemical Bulletin
Abstract
1. The behavior of 1,4-dichlorobutane in direct synthesis was investigated. It was shown that the main reaction product is 1,1-dichlorosilacyclopentane. 2. The reaction of 1,1-dichlorosilacyclopentane with sulfuryl chloride, acetic anhydride, allylmagnesium bromide, and aqueous alkali were studied. 3. 1,1,3-Trichlorosilacyclopentane, which is formed in the chlorination of 1,1-dichlorosilacyclopentane, undergoesΒ-decomposition with opening of the ring when it reacts with a Grignard reagent.