I. Bally, E. Gǎrd, E. Ciornei
1975
Citations
0
Influential Citations
3
Citations
Journal
Journal of Labelled Compounds and Radiopharmaceuticals
Abstract
The synthesis of n-heptane-1-14C is described. starting from 14CH3I via (14CH3) 2Cd and caproyl chloride; for obtaining n-heptane-2-14C, n-pentyl bromide is converted into the Grignard reagent, carbonated with 14CO2, and the resulted coproic acid is converted into its chloride and treated with dimethyloadmium. In both cases the labelled n-heptan-2-one is finally reduced to labelled n-heptane by the Kishner-Wolff method.