P. Powell
Jan 22, 1974
Citations
0
Influential Citations
36
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract The polymeric, halogen-bridged complex [(diene)RuX2]n (where diene = 1,5-cyclooctadiene) reacts with acetylacetone, benzoylacetone, salicylaldehyde, 2-mercaptopyridine, 8-hydroxyquinoline and 2-mercaptobenzthiazole in hot dimethylformamide in the presence of sodium carbonate, to give chelate complexes [(diene)ruthenium(chel)2]. Two geometrical isomers of 1,5-cyclooctadiene bis(benzoylacetonato)ruthenium(II) have been characterised. Diene bis(dimethyldithiocarbamato)ruthenium(II) complexes [diene = 1,5-COD or bicyclo[2.2.1]hepta-2,5-diene] are also described.