Qiang Wang, Xingwei Li
Apr 15, 2016
Citations
1
Influential Citations
63
Citations
Journal
Organic letters
Abstract
Nitrosobenzenes have been used as a convenient aminating reagent for the efficient synthesis of 1H-indazoles via rhodium and copper catalyzed C-H activation and C-N/N-N coupling. The reaction occurred under redox-neutral conditions with high efficiency and functional group tolerance. Moreover, a rhodacyclic imidate complex has been identified as a key intermediate.