K. Anand, G. Srivastava, R. C. Mehrotra
1977
Citations
0
Influential Citations
9
Citations
Journal
Synthesis and Reactivity in Inorganic and Metal-organic Chemistry
Abstract
Abstract Reactions of arsenic trioxide with various 1,2-diols (viz., ethane-1, 2-diol; propane-1, 2-diol; butane-2, 3-diol and 2, 3-dimethylbutane-2, 3-diol), 1, 3-diols (viz., propane-1, 3-diol; butane-1, 3-diol and 2-methyl-pentane-2, 4-diol) and pentane-1, 5-diol in 1:2 and 1:3 molar ratios give the corresponding 2, 2′-oxybis (1, 3, 2-diox-arsolanes and -arsinanes) and 2,2′-alkylenedioxybis-(1, 3, 2-diox-arsolanes and -arsinanes) respectively as volatile liquids which are susceptible to hydrolysis. 2-Chloro-1, 3, 2-diox-arsolanes and -arsinanes can be synthesized in quantitative yields by reactions of the latter types of derivatives with arsenic trichloride.