Kazuhiro Maruyama, Tetsuo Otsuki
1977
Citations
0
Influential Citations
6
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
Upon the irradiation of a benzene solution of 2,3-dichloro-1,4-naphthoquinone, 1, and furan derivatives, 2, 2-chloro-3-(2-furyl)-1,4-naphthoquinones, 3, were obtained, accompanyed by a liberation of hydrogen chloride. The formation of a CT-complex between 1 and 2 was essential for the progress of the reaction. The 1H-CIDNP signals which were observed during irradiation suggest an intervention of a radical pair in the reaction.