A. R. Derzhinskii, L. Konyushkin, P. V. Vershinin
Apr 1, 1976
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Journal
Russian Chemical Bulletin
Abstract
1. The corresponding 2-chloroethyl alkyl(phenyl) sulfones were obtained in high yield by oxidizing the 2-hydroxyethyl alkyl(phenyl) sulfides with chlorine in water; the dehydrohalogenation of the former in the presence of bases yields the corresponding vinyl sulfones. 2. The generality of the oxidative chlorination for 2-hydroxyethyl alkyl(phenyl) sulfides, which have no branching in the α-position to the sulfur atom, was demonstrated.