M. Yamauchi, M. Morimoto, T. Miura
Jan 13, 2010
Citations
0
Influential Citations
103
Citations
Quality indicators
Journal
Journal of the American Chemical Society
Abstract
A denitrogenative annulation reaction of 1,2,3-benzotriazin-4(3H)-ones with allenes catalyzed by a nickel-phosphine complex to produce a variety of substituted 3,4-dihydroisoquinolin-1(2H)-ones in a regioselective manner is described. A highly enantioselective version, as well as structural evidence for the mechanistic course of this reaction, is also presented.