Gan Xiao-xian
2005
Citations
0
Influential Citations
2
Citations
Journal
Chinese Journal of Explosives and Propellants
Abstract
3-Hydroxymethyl-3-methyl oxetane (HMMO) was prepared by the cyclization of raw materials 1,1,1-tri(hydroxylmethyl) ethane and diethyl carbonate.Under lower temperature,3-methoxytosyl-3-methyl oxetane(MTMO) was synthesized by the reaction of HMMO with 4-toluenesulfonylchloride.3-Azidomethyl-3-methyl oxetane was synthesized by the reaction of MTMO and sodium azide.The yields of the three steps were 76%,96%,85%, respectively .The structure and properties of AMMO were identified by ~1HNMR,FTIR,elemental analysis and DSC .The results show that final product was target compound.AMMO was an important energetic oxetane monomer .It can conduct steady cationic polymerization.