K. Majumdar, D. Das, A. Khan
Nov 1, 1988
Citations
0
Influential Citations
24
Citations
Journal
Synthetic Communications
Abstract
Abstract 1-Aryloxy-4-(4′-coumarinyloxy) but-2-yne (1) on refluxing in chlorobenzene gave 4-aryloxymethyl-2H-pyrano 3,2-c benzopyran-5H-one as the single product in almost quantitative yield. All the eight butynes studied underwent 3,3,7 sigmatropic rearrangement at the 4-(4′-coumarinyloxy) propynyl part to give pyranocoumarin derivatives and no furanocoumarin derivative was formed at all.