K. Naemura, M. Komatsu, H. Chikamatsu
Apr 1, 1986
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0
Influential Citations
1
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Journal
Bulletin of the Chemical Society of Japan
Abstract
6-Isopropylidenetricyclo[3.3.0.03,7]octane-2-carboxylic acid (11) was prepared from the dimethylfulvene–ethyl acrylate adduct 5. Optical resolution of 11 was carried out via the (+)-1-(2-naphthyl)ethylamine salt, and (−)-11 was transformed into (−)-6-oxotricyclo[3.3.0.03,7]octane-2-carboxylic acid (14) whose absolute configuration and absolute rotation were established.