M. Shimizu, Y. Watanabe, H. Orita
Jun 1, 1992
Citations
0
Influential Citations
24
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
2,4,6-Trimethylphenol was effectively oxidized to trimethyl-p-benzoquinone with molecular oxygen in the presence of a catalytic amount of copper(II) chloride–amines in alcohol at ambient temperature. Various amines could be used as a co-catalyst in the presence of acids, and especially hydroxylamine hydrochloride and acetone oxime coupled with hydrochloric acid showed high activity. 2,6-Dimethyl-p-benzoquinone was also obtained from 2,6-dimethylphenol in good yield in this catalytic oxidation system.